Spanning about 9.7 million square miles (or 25 million square kilometers), the ozone hole over the South Pole reached its maximum annual size on September 14, becoming the fifth largest on record, they said.
The largest Antarctic ozone hole ever recorded occurred in 2006, at a size of 10.6 million square miles (27.5 million square km), a size documented by NASA's Earth-observing Aura satellite, LiveScience reported.
The Antarctic ozone hole was first discovered in the late 1970s by the first satellite mission that could measure ozone, a spacecraft called POES and run by the National Oceanic and Atmospheric Administration (NOAA).
The hole has continued to grow steadily during the 1980s and 90s, though since early 2000 the growth reportedly leveled off. Even so scientists have seen large variability in its size from year to year.
Intense cold in the upper atmosphere of the Arctic last winter activated ozone-depleting chemicals and produced the first significant ozone hole ever recorded over the high northern regions, the scientists reported in journal Nature.
On the Earth's surface, ozone is a pollutant, but in the stratosphere it forms a protective layer that reflects ultraviolet radiation back out into space, protecting us from the damaging UV rays.
The international ban of ozone-destroying chemicals like CFC's (chlorofluorocarbons) has helped to reduce the loss of protective ozone. Even so, these compounds are still in the stratosphere where they slowly break down over time.
The ozone "hole" is not a complete depletion of ozone throughout the entire atmosphere, but rather the partial or complete depletion of ozone between 8.7 to 13.7 miles (14 to 22 km) above Earth's surface.
This year, for the first time scientists also found a depletion of ozone above the Arctic that resembled its South Pole counterpart.
"For the first time, sufficient loss occurred to reasonably be described as an Arctic ozone hole," the researchers wrote in an article in the journal Nature.
On 27 October, 2011, the NASA NPP satellite will launch, carrying its Ozone Mapper Profiler Suite (OMPS). The advanced sensors on OMPS are expected to provide more accurate measurements of the total area of the ozone hole while also measuring how the concentration of ozone changes vertically throughout the atmosphere.